combined chapter 2 test 1st year

Grand Test#1       CHEMISTRY          1ST YEAR
Time: 1:30 minutes Chapter :01,02,08,09,10,11               Marks: 44
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Q.no1: MULTIPLE CHOICE QUESTIONS:                                     (12x1=12)
1) Molecularity of a chemical reaction:
                       a) cannot be less than 2                       b) can have a fractional value        
                      c) can be zero                                       d) is always a whole number    
              2) when a reaction proceeds in a sequence of steps the overall rate is determined by
                        a) fastest step                                     b) slowest step    
                        c) order of different step                    d) molecularity of all step
              3) In acidic media, oxygen atoms are balanced by adding:
a) H2O                        b) OH-                         c) O                                         d) none
              4) Conversion of chemical energy into electrical energy is done in:
a) voltaic cell             b) galvanic cell         c) electrolytic cell                  d) both a and b
             5) Oxidation potential of zinc is:
a) -0.34V                                b) +0.76V                               c) +0.34V                   d) -0.76V
)           6) Elevation of boiling point is directly related with:
            a) ppm                        b) %w/w solution      c) molarity                              d) molality
             7) The number of water molecules attached to SO4-2  in CuSO4 is:
            a) 1                             b) 2                                         c) 3                              d) 4
     
                8) Molal boiling point constant of ethanol for 1molal solution is:
            a) 1.75 C0                  b) 2.70 C0                  c) 0.52 C0                               d) 79 C0
                9) A substance, which retards the rate of a reaction is called.                                                                   
                        a) Inhibitor                   b) Activator                       c) Autocatalyst            d) None                                      
                10) The  acid hydrolysis of ethyl acetate in the presence of mineral acid is   
                       a)  zero order                                                 b) first order    
                       c) pseudo first order                                     d) second order
                 11) If the product of a reaction itself acts as a catalyst as K [H2] [Br2] ½ is
                       a) homocatalysis          b) autocatalysis              c) negative catalysis          d) heterocatalysis   
                  12) the order of a reaction can be
                         a) positive integer                   b) zero                             c) in fraction                               d) All                                                                                                                                                                                                                                                                                                                                                                                                                       
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Q.no2. SHORT QUESTIONS:                                          (2x10=20)

1) Define zeotropic and azeotropic mixtures with examples                         
2) Differentiate between positive and negative deviation from Raoult’s law.
3) Differentiate between cryoscopic and ebullioscopic constant.
4) What is the function of salt bridge?
5) Differentiate between electrolytic and voltaic cell.
6) Define electrochemistry.
7) A catalyst is specific in its action. Give reason
8) The radioactive decay is always a first order reaction. How?
9) Define activation energy and activated complex.
10) How does a catalyst effect the reversible chemical reactions?

Q.no3 EXTENSIVE QUESTIONS:                                             (4+4+4)

a.   Write a detailed note on Solvent Extraction.


b.   Write a note on Arrhenius equation.  
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Grand Test#2       CHEMISTRY          1ST YEAR
Time: 1:30 minutes       Chapter :03,04,05                         Marks: 40
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Q.no1: MULTIPLE CHOICE QUESTIONS:                                     (12x1=12)
1. For which law, temperature and pressure are constant?
a) Boyle’s law         b) Graham’s law               c) Charles law         d) both a & b
2. The sum of mole fraction of all the 10 different components in mixture is:
a) 4                             b) 3                             c) 10                           d) 1
3. Pressure of water vapors is also called as:
a) Aqueous tension           b) diffusion               c) effusion                d) viscosity
4. The color of NO2 gas is:
a) Yellow                  b) colorless               c) brown                  d) red
5. Which of the following is pseudo solid?
a) CaF2                        b) glass                       c) NaCl                       d) all of these
6. Acetone and chloroform are soluble in each other due to:
a) London force                                b) dipole dipole force  
c) Debye force                                  d) hydrogen bonding
7. Hydrogen bonding is responsible for:
a) Cleansing action of soap     b) tensile strength of fiber             
c) Double helix of DNA              d) all of these
8.Iodine is solid while chlorine is gas because of:
a) Debye force      b) dipole dipole force      c) London force        d) all of these     
9.In Milikan Oil Droplet method, air inside chamber is ionized by:
a)     X rays         b) alpha rays                         c) beta rays              d) none of these
10. The unit of frequency is:
a) Hertz            b) sec-1                    c) cycle per second                    d) all
11. Who suggested the elliptical shape of orbits?
a) bohr                       b) Rydberg       c) Milliken                            d) Sommerfield
12. The heaviest particle among all four given particles is:
a) meson                           b) proton                               c) neutron                 d) electron

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Q.no2. SHORT QUESTIONS:                                          (2x10=20)

1.      What are the causes for deviation from non ideality?
2.      What are the characteristics of plasma? 
3.      Give two uses of plasma.
4.      Water vapours don’t behave ideally at 273K why?
5.      Heat of sublimation of iodine is very high as compare to other halogens. Why?
6.      Why is lattice energy of LiCl higher than that of NaCl?
7.      why ionic solids are brittle? Explain.
8.      State Moseley’s law. Give its application
9.      How would you prove that cathode rays are negatively charged?
10. Why is e/m value of positive rays always less than that of electron?


Q.no3 EXTENSIVE QUESTIONS:                                             (4+4)

a)  Explain Boyle’s law and Avogadro’s law from kinetic molecular equation.
b)  Write a comprehensive note on Quantum numbers.

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